If you get the following error while transfering an account in cPanel/WHM
1. Login to mysql and search if a Database user really exists in the MySQL DB
SELECT user FROM mysql.user;
2. If the user exists, drop the user using
DROP user <db_username>;
3. If the user does not exists in MySQL database, then remove the conflicting Database Owner in the below files
vi /var/cpanel/databases/users.db
and
vi /etc/dbowners
Once this is done, try to transfer the account again and hopefully this time it should complete without any errors.